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Conjugated Carbon-Centered and Nitrogen Radicals by H. Fischer (auth.), H. Fischer (eds.)

By H. Fischer (auth.), H. Fischer (eds.)

Volume II/17 c is the 3rd a part of a complement to the pre- vious compilations II/1 and II/9 a-d2 on magnetic homes of loose radicals released in 1965 and 1977-1980, which lined the literature as much as 1975. as a result of the nonetheless very fast improvement of the sphere and the inclusion of recent sub- jects, the complement masking the interval 1975-85 needed to be cut up into subvolumes, that allows you to look in quick succession. Togetherwith the ealier volumes, II/17 deals an updated and entire surveyand a suite of information on impor- tant chemical intermediates.

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Of DTBP in the presence of corresp. O]hex-2-ene/ DTBP: corresp. 210 76Susl 93) Phot. of DTBP in the presence of corresp. O]hex-2-ene/ DTBP: corresp. 039 79Susl 93) Phot. of DTBP in the presence of corresp. 207 79Luel 3’ yi” D I I “) Assignments based on INDO calculations. ‘3) l&Sigmatropic rearrangement follows from the statistical distribution of deuterium in the cyclohexadienyl radical formed in adamantane matrix. I Substance G&DO1 H Generation/ Matrix or Solvent Method/ T&l bT1 Phot. of DTBP in the presence of corresp.

Radical also generated in adamantane matrix, observable up to 373 K. O]heptenyl radical is observed. / add. Ref. lo2 Substance Generation/ Matrix or Solvent Method/ TM GH, Phot. l]oct-2-ene/ Neat or CF,C12 ESR/ 203 Phot. 1Joct-Zene/ Cyclopropane ESR/ 153 Phot. / add. Ref. 135 78Kawl Phot. 135 78Susl *06), 78Sus2 Phot. I~ 8 5 3 PGH, 11’ 5 3 lo6) INDO calculationof coupling constants. / add. Ref. X-irr. of corresp. 40 78Sus2 X-irr. of corresp. 40 78Sus2 X-irr. of corresp. 40 78Sus2 Phot. 121 78Kawl Phot.

5 Generation/ Matrix or Solvent Method/ TM 3 MeV e-irr. / add. Ref. 15 Bicyclic ally1 radicals D W ’I D * H ’ 5 $H 21 tY 3 4 N-WI ’ H 1 5 hH D2’ -d- . 4 :C,H8DO] ’ 3 H CH,OH 2; Phot. of DTBP in the presence of corresp. O]hex-2-ene/ DTBP: corresp. 210 76Susl 93) Phot. of DTBP in the presence of corresp. O]hex-2-ene/ DTBP: corresp. 039 79Susl 93) Phot. of DTBP in the presence of corresp. 207 79Luel 3’ yi” D I I “) Assignments based on INDO calculations. ‘3) l&Sigmatropic rearrangement follows from the statistical distribution of deuterium in the cyclohexadienyl radical formed in adamantane matrix.

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