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Carbohydrate Chemistry by Royal Society of Chemistry, Robert J. Ferrier

By Royal Society of Chemistry, Robert J. Ferrier

Carbohydrate Chemistry presents evaluation insurance of all guides correct to the chemistry of monosaccharides and oligosaccharides in a given 12 months. the volume of study during this box showing within the natural chemical literature is expanding as a result of greater significance of the topic, particularly in components of medicinal chemistry and biology. In no a part of the sector is that this extra obvious than within the synthesis of oligosaccharides required by way of scientists operating in glycobiology. Clycomedicinal chemistry and its reliance on carbohydrate synthesis is now rather well proven, for instance, via the instruction of particular carbohydrate- established antigens, specially cancer-specific oligosaccharides and glycoconjugates. insurance of issues equivalent to nucleosides, amino-sugars, alditols and cyclitols additionally covers a lot examine of relevance to organic and medicinal chemistry. every one quantity of the sequence brings jointly references to all released paintings in given parts of the topic and serves as a entire database for the energetic learn chemist professional Periodical reviews offer systematic and particular evaluation insurance in significant parts of chemical learn. Compiled by way of groups of top gurus within the appropriate topic components, the sequence creates a distinct provider for the lively examine chemist, with commonplace, in-depth bills of development particularly fields of chemistry. topic insurance inside of diverse volumes of a given name is identical and ebook is on an annual or biennial foundation.

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Extra resources for Carbohydrate Chemistry

Sample text

7 Deoxy-sugar Disaccharides. 6)-P-~-Glc, have been made. 8 Sugar Acid Disaccharides. ’96The O-pivaloated glycosyl bromide of methyl glucuronate can be used to effect 6-P-glycosylationof methyl P-D-galactopyranosidewith 78 % efficiency provided A valuable observathe acceptor is used after treatment with dibutyltin tion was made when thioglycoside 102 was condensed with a 1:l mixture of aand 6-acceptors 103. The p-anomer was the more reactive, the products 104 having the a,P ratio 1:4 (Scheme 8), which was interpreted as implying that the hydroxyl group of the latter anomer was more strongly hydrogen bonded intramolecularly to the ring oxygen atom.

8 Sugar Acid Disaccharides. ’96The O-pivaloated glycosyl bromide of methyl glucuronate can be used to effect 6-P-glycosylationof methyl P-D-galactopyranosidewith 78 % efficiency provided A valuable observathe acceptor is used after treatment with dibutyltin tion was made when thioglycoside 102 was condensed with a 1:l mixture of aand 6-acceptors 103. The p-anomer was the more reactive, the products 104 having the a,P ratio 1:4 (Scheme 8), which was interpreted as implying that the hydroxyl group of the latter anomer was more strongly hydrogen bonded intramolecularly to the ring oxygen atom.

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