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Amino Acids and Peptides (SPR Amino Acids, Peptides by J. H. Jones

By J. H. Jones

Professional Periodical studies supply systematic and specified evaluation assurance of development within the significant parts of chemical study. Written by way of specialists of their professional fields the sequence creates a special provider for the lively study chemist, offering normal serious in-depth money owed of development specifically parts of chemistry.

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Extra resources for Amino Acids and Peptides (SPR Amino Acids, Peptides (RSC))vol.23

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N-Methyl-D-aspartic acid hydrate io an important natural protein amino acid derivative that. has been included in this year's published X-ray work as has L-lanthionine. N-acety1amino)-U-n-butylnorleucine,'"' and Na-acetyl-N-methylL-tryptophanamide 3"5 The crystal structure of the intensely sweet L-aspartamidc (51 1, an . inverso-dipeptide been reported . derivative from one structural point. r. r. heir own right. r. studies continue to provide practical analytical support for amino acid studies, as in assignments of absolute configuration to amethyl a-amino acids through detection of the precise chemical shift for the methyl proton resonances in aqueous solutions containing the chiral lanthanoid shift c u r o ~ i u m ~ I I I ) .

LS2 Pyroglutamic acid processing C + N-Boc (S>-pyroglutaminol, and alkylation) gives C2S14S)- and C ~ S , ~ R ) - H O ~ C . C H C N H ~ ) . C H ~ C H ( W Z H ) C C H Z ) ~ P ~ , Cn = 1,3,5), as 4-substituted glutamic acid analogues for neuroexc itatory activity studies. ate,'~'aridolysis after resolution, and cyclization with P h P . Like the corresponding azetidine-2,4-dicarboxylic are of considerable interest as potential agonists of N-methyl-D-aspartate receptors. "' and . - . The simple-chemicalSYElAh- ir Qf.

The maxiniunt yield Amino Acids and Peprides 26 ef glycine is pour at I O X , but. is of a level that suggests that. the results of serendipitous experiments of this type may feature in future production organic processes chemicals that create cocktail of a [though probably not for more or less useful the production of aminu acids! 1 . '" been shown Since HCN synthesis) were to and NHo to be react. 5% yield through presenting these compounds to the erythrose - fornamidine reaction mixture is a convincing proposal for the genesis of this amino acid.

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